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New materials for lithium batteries work

2021-12-15 16:14:08
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Lithium metal batteries:


The basic principle of lithium batteries


Lithium metal batteries are generally batteries that use manganese dioxide as the positive electrode material, lithium metal or its alloy metal as the negative electrode material, and a non-aqueous electrolyte solution.


Discharge reaction: Li+MnO2=LiMnO2


Lithium ion batteries:


Lithium ion batteries are generally batteries that use lithium alloy metal oxide as the battery cathode material, graphite as the battery cathode material and a non-aqueous electrolyte solution.


The reaction on the charging cathode is: LiCoO2 = Li(1-x)CoO2 + xLi++xe-(electrons)


The reaction occurring on the negative side of the charge is: 6C+xLi++xe- = LixC6


Total reaction in the charge cell: LiCoO2 + 6C = Li(1-x)CoO2 + LixC6

电池正极材料,电池负极材料,锂合金金属

Positive electrodes


Anode materials: There are many anode materials available, and the following table shows the common anode active materials currently on the market.


Nickel-cobalt-aluminium ternary

Anode materials

Chemical composition

Nominal voltage

Structure

Energy density

Cycle life

Costs

Security

Lithium cobaltate(LCO)

LiCoO2

3.7 V

Laminar

Medium

Low

High

Low

Lithium manganate(LMO)

Li2Mn2O4

3.6V

Spinel

Low

Medium

Low

Medium

Lithium nickelate(LNO)

LiNiO2

3.6V

Laminar

High

Low

High

Low

Lithium iron phosphate(LFP)

LiFePO4

3.2 V

Peridot

Medium

High

Low

High

LiNixCoyAl(1-x-y)O2

3.6V

Laminar

High

Medium

Medium

Low


Nickel-cobalt-manganese ternary(NCM)

LiNixCoyMn(1-x-y)O2

3.6V

Laminar

High

High

Medium

Low


Anodic reaction: lithium ion embedding during discharge, lithium ion de-embedding during charge. On charging: LiFePO4 → Li1-xFePO4 + xLi+ + xe- On discharging: Li1-xFePO4 + xLi+ + xe- → LiFePO4.


Negative electrode


Negative electrode materials: graphite is mostly used. In addition, lithium metal, lithium alloy, silicon carbon anode, oxide anode material, etc. can also be used for the negative electrode.


Negative electrode reaction: lithium ions are de-embedded when discharging and embedded when charging.


When charging: xLi+ + xe- + 6C → LixC6


When discharging: LixC6 → xLi+ + xe- + 6C


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